Polymer Grafted Nanoparticle Viscosity Modifiers

Simulation of Interaction Forces between Nanoparticles:  End-Grafted Polymer Modifiers.

The interaction forces between nanoscale colloidal particles coated with end-grafted Lennard-Jones homopolymers are calculated using off-lattice Monte Carlo simulations in the NVT ensemble. The focus of this work is on grafted polymers that are of approximately the same size as the nanoparticle, a regime intermediate to the star-polymer and Derjaguin limits. The effects of chain length (N), nan...

Multiscale Modeling of Covalently Grafted Nanoparticle/polymer Nanocomposites

Modeling polymer grafted nanoparticle networks reinforced by high-strength chains.

Using a multi-scale computational approach, we determine the effect of introducing a small fraction of high-strength connections between cross-linked nanoparticles. The nanoparticles' rigid cores are decorated with a corona of grafted polymers, which contain reactive functional groups at the chain ends. With the overlap of neighboring coronas, these reactive groups can form weak labile bonds, w...

Stability of Self-Consolidating Concrete Containing Different Viscosity Modifiers

The main objective of this paper is to assess the effect of different viscosity-enhancing admixture (VEA) types and concentrations on deformability and stability of self-consolidating concrete (SCC). Two polysaccharide-based VEAs, one cellulose-based VEA, and a modified-startch VEA are used in this investigation. Regardless of polymer type, results showed that the incorporation of VEA leads to ...

Laundering durable antibacterial cotton fabrics grafted with pomegranate-shaped polymer wrapped in silver nanoparticle aggregations

To improve the laundering durability of the silver functionalized antibacterial cotton fabrics, a radiation-induced coincident reduction and graft polymerization is reported herein where a pomegranate-shaped silver nanoparticle aggregations up to 500 nm can be formed due to the coordination forces between amino group and silver and the wrapping procedure originated from the coincident growth of...